Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12

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dc.contributor.authorHikmat S. Hilal
dc.contributor.authorShukri Khalaf
dc.contributor.authorWaheed Jondi
dc.date.accessioned2016-09-07T10:16:54Z
dc.date.available2016-09-07T10:16:54Z
dc.date.issued1994
dc.description.abstractIsomerization and hydrosilylation reactions of terminal olefins have been reported under thermal and photochemical conditions using Ru3 (C0) 12, 1, and HRu3 (CO)!!, 2,11 '0 In a very recent work, we reported E LI that 1 catalyses both Isomerization and hydrosilylation reactions of 1-octene (eq. 1). It has been found that the isomerization reaction occurs via lower nuclearity catalytic species that result from fragmentation of the mother cluster 1. Evidence in favour of concurrent cluster catalysis was also reported. On the other hand, the hydrosilylation reaction occurred via cluster catalysis at first and after some-time fragment catalysis occurred.en
dc.identifier1727-2114
dc.identifier.urihttp://hdl.handle.net/20.500.11888/2052
dc.titleShort Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12en
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An-Najah University Journal for Research - A (Natural Sciences)