Cluster Catalysis of Olefin Hydrosilylation and Isomerization Thermal Reaction Using Co4(Co)10(PPh)2

dc.contributor.author	Waheed J. Jondi
dc.date.accessioned	2016-09-07T10:16:46Z
dc.date.available	2016-09-07T10:16:46Z
dc.date.issued	1996
dc.description.abstract	The cobalt cluster [Co4(C0)10(PPh)2], 1/~, has been evaluated as a catalyst for 1-octene thermal hydrosilylation and isomerization reactions. The kinetics indicates that the hydrosilylation reaction occurs via cluster catalysis at temperatures ranging from 50-70°c. The 1 - octene isomerization was selective to trans-2-octene only. The kinetics indicates that at 50°c or lower isomerization reaction occurs via cluster catalysis whereas at 70°c or higher catalysis by lower nuclearity species is involved. The effects of solvent silane temperature and catalyst and reactant concentrations on the rates of hydrosilylation and isomerization reactions have been investigated. Plausible mechanisms based on experimental data have been proposed.	en
dc.identifier	1727-2114
dc.identifier.uri	http://hdl.handle.net/20.500.11888/1927
dc.title	Cluster Catalysis of Olefin Hydrosilylation and Isomerization Thermal Reaction Using Co4(Co)10(PPh)2	en
dc.title	الحفز الحراري لاضافة السايلان وتفاعلات التشكل للألكينات باستخدام الكوبالت العنقودي	ar

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