Modification of CuSe thin film electrodes prepared by electrodeposition: enhancement of photoelectrochemical characteristics by controlling cooling rate and covering with polymer/metalloporphyrin

dc.contributor.authorAl-Kerm, Rola Sultan
dc.date.accessioned2018-01-24T12:57:08Z
dc.date.available2018-01-24T12:57:08Z
dc.date.issued2016-03-23
dc.description.abstractCuSe thin films were prepared on FTO/glass using electrodeposition technique for the purpose of photoelectrochemical (PEC) conversion of light into electricity. Effects of annealing temperature, cooling rate, deposition time, annealing time, and coating with MnP-PE matrix on the film characteristics were investigated for different films using different techniques: AFM, PL spectra, UVVisible spectra, together with PEC parameters including: dark J-V plots, photo J-V plots, value of short-circuit current, open circuit potential and stability. Coating the pre-annealed CuSe thin films significantly enhanced their physical properties and PEC characteristics. Moreover, pre-annealing the coated CuSe films with MnPPE matrix for 2 hrs gave highest conversion efficiency and fill factor (14.3%, 77.4% respectively). This study has come out with a major finding and recommendation that is: Pre-annealing CuSe film electrodes at certain temperature (150oC) for 2 hrs followed by coating with suitable electroactive matrix MnP/PE significantly enhanced their physical properties and PEC characteristics.en_US
dc.identifier.urihttps://hdl.handle.net/20.500.11888/13061
dc.language.isoenen_US
dc.subjectCuSeen_US
dc.subjectthin filmen_US
dc.subjectelectrodepositionen_US
dc.subjectannealingen_US
dc.subjectcooling rateen_US
dc.subjectPECen_US
dc.subjectefficiencyen_US
dc.subjectstabilityen_US
dc.titleModification of CuSe thin film electrodes prepared by electrodeposition: enhancement of photoelectrochemical characteristics by controlling cooling rate and covering with polymer/metalloporphyrinen_US
dc.typeArticleen_US
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