New [CoX2(dmdphphen)] Complexes and their CT-DNA Binding Affininty
| dc.contributor.author | Barakat, Assem | |
| dc.date.accessioned | 2018-01-22T11:03:51Z | |
| dc.date.available | 2018-01-22T11:03:51Z | |
| dc.date.issued | 2015-04-21 | |
| dc.description.abstract | 1,10-Phenanthroline ligands and their derivatives are very attractive in metal complexes [1–3]. Two new neutral mixed-ligand cobalt(II) complexes, [CoCl2(dmdphphen)]1 and [Co(NCS)2(dmdphphen)] 2, where dmdphphen is 2,9dimethyl-4,7-diphenyl-1,10-phenanthroline were made available in very good yields and simple way. These complexes were characterized by an elemen-tal analysis, UV-Vis, IR, TG/DTA, cyclic voltamme-try CV, and single X-ray diffraction. Complex 2 crystallized as monoclinic with a space group P21/c. Co(II) ions are located in a distorted tetrahedral environmentas. TG/DTA result shows that these complexes are very stable and decomposed through one-step reaction. The two complexes exhibit a quasireversible one-electron response at −550 and 580mV. Absorption spectral studies reveal that such complexes exhibit | en_US |
| dc.identifier.uri | https://hdl.handle.net/20.500.11888/12944 | |
| dc.language.iso | en | en_US |
| dc.title | New [CoX2(dmdphphen)] Complexes and their CT-DNA Binding Affininty | en_US |
| dc.type | Article | en_US |
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