Palladium(II)-Catalyzed Dicarboxymethylation of Chiral Allylic Alcohols: Chirality Transfer Affording Optically Active Diesters Containing Three Contiguous Chiral Centers
Date
2011-06-01
Authors
Othman Hamed
Patrick M. Henry
Daniel P. Becker
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Abstract
<p>Pd-catalyzed olefin dicarbonylation of chiral allylic alcohols with chirality transfer affords the chiral alcohol diesters contiguous chiral centers, in good to excellent diastereoselectivities (78- 98%).</p>
<p>Pd-catalyzed olefin dicarbonylation of chiral allylic alcohols with chirality transfer affords the chiral alcohol diesters contiguous chiral centers, in good to excellent diastereoselectivities (78- 98%).</p>
<p>Pd-catalyzed olefin dicarbonylation of chiral allylic alcohols with chirality transfer affords the chiral alcohol diesters contiguous chiral centers, in good to excellent diastereoselectivities (78- 98%).</p>